Octahedral chalcogenide rhenium cluster complexes with imidazole
نویسندگان
چکیده
منابع مشابه
Azide alkyne cycloaddition facilitated by hexanuclear rhenium chalcogenide cluster complexes.
Two hexanuclear rhenium clusters containing azide ligands, [Re6Se8(PEt3)5(N3)]BF4 and [Re6Se8(PEt3)4(N3)2], were synthesized from the analogous pyridine complexes and fully characterized. Studies show that [Re6Se8(PEt3)5(N3)]BF4 reacts with activated alkynes, dimethyl acetylenedicarboxylate and methyl 4-hydroxyhex-2-yneoate, to form the triazolate cluster complexes [Re6Se8(PEt3)5(L1 or L2)]BF4 ...
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ژورنال
عنوان ژورنال: Polyhedron
سال: 2019
ISSN: 0277-5387
DOI: 10.1016/j.poly.2019.03.007